QUANTUM MECHANICS
UNBESTIMMTHEITSRELATION
WERNER HEISENBERG
PARTICLES IN NATURE AND NOT SYNTHETIC PARTICLES
EXACT POSITION
We hereby dissociate quantum mechanics of particles in Nature from classical mechanics as well as modified classical mechanics (ACJ/Chem; communicated to Dorothee Felix, 2005) and in fact, mathematics.
Nature abhors zero. Exact position is 0 position in 0 time which is not practical.
Continuity of track and time, brain and vision, and biological time, particle-brain-apparatus interaction, - we allow +- 15 per cent deviation as exact position.
This is also valid for a 1 mg iron ball.
Madhumita Guha, daughter of Manoj Guha and one of my M.Sc. students lectured on brain and vision. She was an expart on Hilbert Space-Das’s Space.
Ich hab ein Rubin gefunden
Das ist ein Stuck von Rubinstein
Dedicated to the Deity of the Nebulae and of the Rains and in memory of Sister Ivana
I remain since 3000BC
Your Obedient Servant
V. le Soleil
TAPAN K. DAS (GUPTA)
City of Siliguri
D. Phil.
Wednesday, February 3, 2010
Monday, February 1, 2010
its all about QM & Org Syntheses
Quantum Mechanics- Unbestimmtheistsrelation and particle velocity
Quantum Mechanics - Unbestimmtheistsrelation and Particle Velocity
Quantum MechanicsParticle Velocity
Quantum Mechanics - Unbestimmtheistsrelation and Particle Velocity
Usually 32 ft per second. You may think of velocity of an electron in Bohr orbit (Niels Bohr Calcutta 1959). Continuity of track and time, and exact position unavailable.Nature abhors zero. This is fundamental indeterminacy. Fundamental indeterminacies are also achieved if origin in the co-ordinate system is not 000. Life throbs everywhere. Positional error, delta x may be as small as z which is indeterminate but never 0.
Gruss Gott
Tapan K. Das (Gupta)
le Soleil (b. 1941, Krishnagar)
formerly of the ETH/ Zurich (1969-2005) and University of North Bengal (1972-2006)
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004
Personal Code No: 575-39(40)-04
Organic Syntheses: Common Reactions in Organic Syntheses
Learn to use sodamide as well as moist ether.
Benzyl alcohol producing ethers and esters.
Similarly, methyl substituted benzyl alcohols.
Pure sodium phenoxide, monosodio salts of benzene diols.
Prepare analytically pure benzene and spectroscopically pure ethanol in bulk.
Oxidize para-xylene in bulk.
Learn to handle glyoxal in bulk. Prepare formamidonitrone.
Dihydronaphthalene- handle with care.
Learn why calcium (SANDOZ since 1941) is needed for proper functioning of vitamin C in human body.
Pyridine-1-oxide plus phenyl methyl propiolate in 50:1 molar ratio in dry and refluxing benzene and tolune. As concentrated a solution as possible. Isolate the product in pure form.
Try chlorination with N-chlorosuccinimide in ice cold carbon tetrachloride. Succinimide floats in carbon tetrachloride. (this was a hint from Albert Eschenmoser, Zurich ETH, 1970). Bulk purchase of NClS.
Thermal and conrotatory electrocyclic reactions of butadienes.
Use C-2 symmetry operation if you want to draw a symmetry-allowed correlation diagram. Hydrogen atom cannot stay in one of its spin degenerate states.
Concept of a Greek pi: sphere ingrained in pi in Physical Chemistry and meaning of pi squired. (Riemannian pi is a different chapter)
Otherwise you could as well write 22.000001/7for pi. What harm? Determination of exact position of a moving particle is impossible.
Chemists all over the world unite
T K Das (Gupta)
City of Siliguri
& City of Calcutta- a City of hard toil and not of beggars. No food if you do not work.
QUANTUM MECHANICS AND ORGANIC MOLECULES
QUANTUM MECHANICS AND ORGANIC MOLECULES
Spin-degenerate States and Square
Square
T.K. Das (Gupta)
City of
(West)
QUANTUM MECHANICS SPIN
QUANTUM MECHANICS SPIN
Quantum Mechanics
Spin
Spin-degenerate states
Planar C8H8 and Spin-degeneracy
Benzene and Electronic Closed-Shell
Planar C8H8 cannot stay in one of its spin-degenerate states.
Hydrogen atom?
Adolf von Bayer’s centric formula of benzene, and dibenzene AgBFψ (Fluka Buchs 1970-1971 and ETH / Zürich)
Merci bien
TAPAN K. DAS GUPTA
D.Phil.
City of Siliguri
24 August 2009
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004
Personal Code No: 575-39(40)-04
QUANTUM MECHANICS SPIN
Quantum Mechanics is ‘not in a spin’.
A spinning proton generates a tiny bar magnet.
Spin in a silver atom, reference: Stern and Gerlach’s experiment. This is widely discussed in the treatise QUANTUM MECHANICS by Lokanathan and Ghatak.
With all my best wishes
Tapan K. Das Gupta
D. Phil.
City of Siliguri
Modified Classical Mechanics: Continuity of Track and Time
Modified Classical Mechanics Continuity of Track and Time
Classical MechanicsModified Classical MechanicsContinuity of Track and timePosition can only be determined at zero-time which is unavailable. As a result,
Tapan K. das (Gupta)
D.Phill.City of Siliguri
QUANTUM MECHANICS- New Thought
QUANTUM MECHANICS
Ur Quantum Mechanics: Werner Heisenberg: Determination of Exact Position
Particle velocity, 32 ft per second
Exact position by induced kinetic energy drop, k.e. never being zero
Be satisfied with this proceejer
Time is fixed (Time reservoir) and delta p(x) appears
With steady p(x) a Strich (particle-apparatus-brain interaction)
This is delta x
With all my best wishes
Tapan K. Das (Gupta)
D. Phil.
City of Siliguri
Modified Classical Mechanics Continuity of Track and Time
Classical Mechanics
Modified Classical Mechanics
Continuity of Track and time
Position can only be determined at zero-time which is unavailable. As a result,
Tapan K. das (Gupta)
City of
Classical Mechanics Modified Classical Mechanics Continuity of Track and time
Classical Mechanics
Modified Classical Mechanics
Continuity of Track and time
Position can only be determined at zero-time which is unavailable. As a result,
Tapan K. das (Gupta)
City of
Quantum Mechanics- Spin Degenerate States
Aufbau hydrogen (Das) cannot stay in one of its spin degenerate states.
Spin-pairing is intrinsic.
A Proverb: “Crops need rain”
From:
Tapan K. Das (Gupta)
D. Phil.
City of
DOROTHEE FELIX
Organic SynthesesOrganic Syntheses- Hydroxyepoxides and Keto-epoxides
DOROTHEE FELIX is 80
Epoxides of 4-vinyl cyclohexanone and 3-vinyl cyclohexanol. Medium-ring equivalents.
Aziridines of the vinyl group.
bien
Tapan K. Das
City of Siliguri,
12 January, Mondi evening
2009
Zero Time: Speeding Particles in Nature- Determination of Exact Position
PARTICLES
PARTICLES IN NATURE
Speeding Particles in Nature- Determination of Exact Position
Needs zero time which is unavailable; ‘stops and starts again?’
Zero time and length of time, t is real time: incongruous.
Keep in mind continuity of track and time and ‘biological time’.
Posted by
Tapan K. Das Gupta
Formerly of ETH, Zurich and NBU, West Bengal, India
D.Phil.
City of Siliguri
27 August, 2009
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004Personal Code No: 575-39(40)-04
QUANTUM MECHANICS SPIN
QUANTUM MECHANICS SPIN
Quantum Mechanics is ‘not in a spin’.
A spinning proton generates a tiny bar magnet.
Spin in a silver atom, reference: Stern and Gerlach’s experiment. This is widely discussed in the treatise QUANTUM MECHANICS by Lokanathan and Ghatak.
With all my best wishes
Tapan K. Das Gupta
D. Phil.
City of Siliguri
ZERO- THE TIME AND POSITION (PARTICLE AT REST: ZERO POSITION)
ZERO- THE TIME AND POSITION
PARTICLE AT REST: ZERO POSITION
Integrating Φ² from ZERO to Infinity
Zero is nothingniss in the realm of physical science and Nature abhors zero.
Tapan K. Das (Gupta)
ORGANIC SYNTHESES- PERFUMERY
ORGANIC SYNTHESES: PERFUMERY
gamma- BUTYROLACTONES
A SPIROLACTONE
Reference:
A. Eschenemoser et. al., Helv. Chim. Acta. 1972, 1973
A matching lactone from G. Ohloff, Firmenich,
Merci
TAPAN K. DAS (GUPTA)
DOROTHEE FELIX
Sonnenbergstrasse 20
CH- 8032 Zürich
ORGANIC SYNTHESES- PERFUMERY
ORGANIC SYNTHESES: PERFUMERY
gamma- BUTYROLACTONES
A SPIROLACTONE
Reference:
A. Eschenemoser et. al., Helv. Chim. Acta. 1972, 1973
A matching lactone from G. Ohloff, Firmenich,
Merci
TAPAN K. DAS (GUPTA)
and
DOROTHEE FELIX
Sonnenbergstrasse 20
CH- 8032 Zürich
ORGANIC SYNTHSES- ALDEHYDE- AMMONIA AND CYANHYDRIN OF RIBOSE
ORGANIC SYNTHSES- ALDEHYDE- AMMONIA AND CYANHYDRIN OF RIBOSE
Biosyntheses: Keep pituitary mildly active- not always.
Secretions mix with blood and you are fit.
TAPAN K. DAS (GUPTA)
D.Phil.City of Siliguri
ORGANIC SYNTHESES: PEPTIDES
ORGANIC SYNTHESES: PEPTIDES
A Passage from Prebiotic Chemistry to Creation of Biosphere
Biochemistry
Ribose to Ribosyl cyanide to Ribosyl amide to Peptides
Merci
TAPAN K. DAS GUPTA
D.Phil.
City of Siliguri
Orbital Symmetry: Electrocyclic Reactions
Orbital Symmetry: Electrocyclic Reactions
Conservation of Orbital Symmetry
Thermal and Conrotatory Electrocyclic Reaction of Butadiene
Orthogonality of Sigma and Pi in Cyclobutene and Apparent Deviation in Drawing Correlation Diagram
Butadiene at elevated temperatures and cis-Butadiene; barrier to rotation less than 26 Kcal per mole. Shi (S) and shi (A) are initially orthonormalized and state function is totally symmetric. Cyclobutene: sigma (S) and pi (S) which are orthoganol to the true sense of the word. Hence thermal correlations
shi (S) ------ sigma (S) and
shi (A) ------ pi (S) allowed.
bien
T. K. Das
le Soleil (b. 1941, Krishnagar)
formerly of the ETH/ Zurich (1969-2005) and University of North Bengal (1972-2006)
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004
Personal Code No: 575-39(40)-04
ITS ALL ABOUT QUANTUM MECHANICS0 comments 
Orbital Symmetry: Electrocyclic Reactions
Orbital Symmetry: Electrocyclic Reactions
Conservation of Orbital Symmetry- Thermal Electrocyclic Reactions- Exp (t), die Zeit as Fourth Co-ordinate of Albert Einstein (1956) J.C. Slater and Andrew Streitwieser Jr’s 2px orbital (Molecular Orbital Theory for Organic Chemists, 1961- a classic) on 90 degree rotation (C-4 point group symmetry operation. F. Albert Cotton) is 2pz orbital of carbon atom which is 6-fold spin-degenerate (Jyotirmoy Saha) and 0.5 means 50% probability. This orbital is u (ungerade). Call this ‘phi’. Phi may undergo mathematical replication. Consider a mathematical ensemble of four phi. Ritz-splitting of each phi needs a and b, and splitting pattern is a (phi), b (phi), -b (phi) and –a (phi) [even parity Engene Wigner and mirror images). Write a for a (phi) and b for b (phi). Symmetric and Antisymmetric Linear Combinations (LC’s, Robert S. Mulliken- a special lecture) which are Associations and Dissociations produce
a -b b -a A
b -a -a b S
b a -a -b A
a b b a S
(a b) matrix similarly (zero) matrix for allyl
Coefficients a and b: b > a,
2 (a squired + b squired) is nearly 1 (1 being pure and unavailable) and as a à 0, b à 1
You may explain thermal and conrotatory electrocyclic reaction (Robert Burns Woodward and Roald Hoffmann).
Call a = 0.371 and b= 0.600 (Andrew Streitwieser Jr and Jerry March).
Space in Mathematics is infinite extension, r being insignificantly curved like t, the fourth coordinate of Albert Einstein (1956).
Exp(-cr) is 1- (+cr) + (+cr)squired/2 – (+cr)cubed/6 +…
This infinite series (Leonhard Euler,
Streitwieser’s (1961) beta is alpha multiplied by S so that S=0 in secular equations, is not a ‘crude approximation’. (Peter Debye and his Assistant, Huckel)
Hydrogen Molecule: p+ q = p(1+S), p being -13.59 or -13.60 eV (Harry B. Gray, 1965)
The Author thanks Roald Hoffmann and apologizes to William N. Lipscomb. This is personal. Kurt Schaffner, Dorothee Felix, Duilio Arigoni and E.J.Cory- a Happy 80.
Tapan K. Das (Gupta)
Bethuadahari-Enginepur
Dt. Nadja
Tapan K. Das (Gupta) D.Phil.
le Soleil (b. 1941, Krishnagar)
formerly of the ETH/ Zurich (1969-2005) and University of North Bengal (1972-2006)
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004
Personal Code No: 575-39(40)-04
Orbital Symmetry: Electrocyclic Reactions
Orbital Symmetry: Electrocyclic Reactions
Conservation of Orbital Symmetry
Thermal and Conrotatory Electrocyclic Reaction of Butadiene
Orthogonality of Sigma and Pi in Cyclobutene and Apparent Deviation in Drawing Correlation Diagram
Butadiene at elevated temperatures and cis-Butadiene; barrier to rotation less than 26 Kcal per mole. Shi (S) and shi (A) are initially orthonormalized and state function is totally symmetric. Cyclobutene: sigma (S) and pi (S) which are orthoganol to the true sense of the word. Hence thermal correlations
shi (S) ------ sigma (S) and
shi (A) ------ pi (S) allowed.
bien
T. K. Das
le Soleil (b. 1941, Krishnagar)
formerly of the ETH/ Zurich (1969-2005) and University of North Bengal (1972-2006)
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004
Personal Code No: 575-39(40)-04
ITS ALL ABOUT QUANTUM MECHANICS0 comments
Orbital Symmetry: Electrocyclic Reactions
Orbital Symmetry: Electrocyclic Reactions
Conservation of Orbital Symmetry- Thermal Electrocyclic Reactions- Exp (t), die Zeit as Fourth Co-ordinate of Albert Einstein (1956) J.C. Slater and Andrew Streitwieser Jr’s 2px orbital (Molecular Orbital Theory for Organic Chemists, 1961- a classic) on 90 degree rotation (C-4 point group symmetry operation. F. Albert Cotton) is 2pz orbital of carbon atom which is 6-fold spin-degenerate (Jyotirmoy Saha) and 0.5 means 50% probability. This orbital is u (ungerade). Call this ‘phi’. Phi may undergo mathematical replication. Consider a mathematical ensemble of four phi. Ritz-splitting of each phi needs a and b, and splitting pattern is a (phi), b (phi), -b (phi) and –a (phi) [even parity Engene Wigner and mirror images). Write a for a (phi) and b for b (phi). Symmetric and Antisymmetric Linear Combinations (LC’s, Robert S. Mulliken- a special lecture) which are Associations and Dissociations produce
a -b b -a A
b -a -a b S
b a -a -b A
a b b a S
(a b) matrix similarly (zero) matrix for allyl
Coefficients a and b: b > a,
2 (a squired + b squired) is nearly 1 (1 being pure and unavailable) and as a à 0, b à 1
You may explain thermal and conrotatory electrocyclic reaction (Robert Burns Woodward and Roald Hoffmann).
Call a = 0.371 and b= 0.600 (Andrew Streitwieser Jr and Jerry March).
Space in Mathematics is infinite extension, r being insignificantly curved like t, the fourth coordinate of Albert Einstein (1956).
Exp(-cr) is 1- (+cr) + (+cr)squired/2 – (+cr)cubed/6 +…
This infinite series (Leonhard Euler,
Streitwieser’s (1961) beta is alpha multiplied by S so that S=0 in secular equations, is not a ‘crude approximation’. (Peter Debye and his Assistant, Huckel)
Hydrogen Molecule: p+ q = p(1+S), p being -13.59 or -13.60 eV (Harry B. Gray, 1965)
The Author thanks Roald Hoffmann and apologizes to William N. Lipscomb. This is personal. Kurt Schaffner, Dorothee Felix, Duilio Arigoni and E.J.Cory- a Happy 80.
Tapan K. Das (Gupta)
Bethuadahari-Enginepur
Dt. Nadja
Tapan K. Das (Gupta) D.Phil.
le Soleil (b. 1941, Krishnagar)
formerly of the ETH/ Zurich (1969-2005) and University of North Bengal (1972-2006)
Permanent address : Dipannita Apartment, Sree Ma Street, South Babupara, Town station, City of Siliguri, District of Darjeeling, India 734004
Personal Code No: 575-39(40)-04
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